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Abstract : The use of N-heterocyclic carbenes as catalysts for organic transformations

has received increased attention in the past 10 years. A discussion of catalyst

development and nucleophilic characteristics precedes a description of recent

advancements and new reactions using N-heterocyclic carbenes in catalysis.

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The fifth edition of the Kirk-Othmer Encyclopedia of Chemical Technology builds upon the solid foundation of the previous editions, which have proven to be a mainstay for chemists, biochemists, and engineers at academic, industrial, and government institutions since publication of the first edition in 1949.

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